Adsorption of methylene blue on activated carbon pdf

Apr 18, 2010 adsorption model corresponding to the methylene blue adsorption by activated carbon is the freundlich adsorption model. It is a versatile adsorbent with high porosity and surface area. Adsorption of methylene blue dye onto activated carbon. Adsorption of methylene blue onto bamboobased activated. Trial activated carbon mg absorbance ratio of methylene blue aa o 1 1 0. Adsorption of methylene blue mb on activated carbon was carried out using a bath experiments method in a rotary shaker at 150 rpm. The resulting activated carbon fcbac was preserved and used as an adsorbent.

Pdf the adsorption of methylene blue mb on activated carbon. Pdf adsorption of methylene blue onto treated activated. Jun 29, 2016 by using the activated carbon obtained from citrullus lanatus rind by zinc chloride activation, methylene blue mb removal from aqueous solutions was studied, and the adsorption mechanism was solved through webermorris intraparticle diffusion model, bangham model, boyd model, fourier transform infrared spectra, and scanning electron microscopy. Among the various types of dyes removed activated carbon has selectively used for removal of methylene blue dye which has been extensively used in the textile industry. Meanwhile, the isotherm adsorption model of the adsorbents against methylene blue follows the langmuir and freundlich equations for eriochrome black t. This parameter can be approximated from the langmuir constant xmusing the expression s xmn a, where n is avogadros number and a is the area of the absorbing molecule. Adsorption of methylene blue onto activated carbon developed from biomass waste by h2so4 activation. Adsorption of methylene blue by an efficient activated carbon. Paper open access adsorption study of methylene blue and.

Nevertheless, adsorption has proven to be potentially powerful because of its imaginable opportunity to design the chemical composition of the adsorbent surface 35. Removal of methylene blue from aqueous solution by activated. Pdf methylene blue adsorption on activated carbon prepared. The experiments were carried out to explore methylene blue mb uptake by. The flasks were agitated on a mechanical shaker for 72 hours at 25 c, at which point the solutions were filtered and the amount of methylene blue.

Wed like to understand how you use our websites in order to improve them. The effect of contact time, solution ph and adsorbent dosage were investigated. Pseudo first order kinetic plot for the adsorption of methylene blue on activated carbon. Preparation of activated carbon using koh as chemical activation 2. Adsorption experiments were conducted and the maximum adsorption capacity was determined. Pdf adsorption of methylene blue on activated charcoal, silica gel. Adsorption of methylene blue in water onto activated carbon by. Adsorption of methylene blue onto microwave oven h2so4 activated carbon 7. Removal of methylene blue from wastewater by adsorption onto.

Carbon nanotubes, methylene blue, basic dye, adsorption, equilibrium, kinetic. Adsorption of methylene blue onto activated carbon produced from. Pdf adsorption of methylene blue onto treated activated carbon. The experimental data were analyzed by the langmuir and freundlich models of adsorption. Adsorption study of methylene blue and eriochrome black t dyes on activated carbon and magnetic carbon composite article pdf available.

Fcbac was characterized by using ftir, sem and eds techniques. Adsorption of methylene blue onto activated carbon derived. The adsorption data was fitted with both langmuir and freundlich adsorption isotherms models. Adsorption isotherm of the methylene blue mb on the activated carbon was determined and correlated with common isotherm equations. Adsorption of methylene blue onto activated carbon produced from steam activated bituminous coal. The effects of initial concentration, agitation time. Activated carbon with large specific surface area 1545 m 2 g. It also shows that, all the activated carbons used during the experiments adsorbed dye from the dye solution more than all the unactivated carbons used for the experiments 11. The activated carbon was used to adsorb methylene blue and congored dyes from model textile effluent obtained from nichemtex nig. Adsorption and photodegradation of methylene blue by iron oxide impregnated on granular activated carbons in an oxalate solution. Adsorption result from activated carbon and magnetic carbon composite on both dyes followed the kinetics model pseudosecond order.

Pdf adsorption of methylene blue on activated charcoal. The textural properties and acidic functional groups of. The capacity of activated carbon for a given pollutant is usually determined by carrying out an adsorption isotherm. Characterization of activated carbon prepared from sludge. Adsorption of methylene blue from aqueous solution onto viscosebased activated carbon fiber felts. Adsorption of methylene blue in water onto activated carbon. An experiment illustrating both the langmuir and freundlich isotherms. Removal of methylene blue from wastewater by adsorption onto zncl 2 activated corn husk carbon equilibrium studies maryam khodaie, 1 nahid ghasemi, 1 babak moradi, 1 and mohsen rahimi 1 1 department of chemistry, sciences faculty, islamic azad university, arak branch, p. High adsorption of methylene blue by activated carbon. Experimental study of methylene blue adsorption from aqueous. However activated carbon has shown significant removal properties with respect to other adsorbents. The shrinkage was considered in three different ways. Adsorption capacity of activated carbon prepared by chemical.

Adsorption of methylene blue by activated carbon blogger. Adsorption of methylene blue from aqueous solution onto. Removal of methylene blue from effluent by using activated. In this study, activated carbon was developed from ficus carica bast fcbac. For the method of langmuir adsorption capacity k is 0. The carbonisation of rsp using zncl 2 rspzncl as activating agent was found the best as compared among the rest which high bet surface area, total pore volume and iodine number were 1689. Lataye published on 20141126 download full article with reference data and citations. Adsorption of methylene blue on activated charcoal, silica gel and silica article pdf available in asian journal of chemistry 172. Due to its high adsorption capacity, activated carbon has a wide range of applications, mostly used as a removing agent for both organic and inorganic materials 1. Adsorption of methylene blue dye onto activated carbon prepared from pongamia pinnata seed written by manoj l. Adsorption of methylene blue onto activated carbon. The adsorption of methylene blue onto koh treated activated carbon 30%ackoh and untreated activated carbon ac has been studied. This investigation describes the adsorption of methylene blue, a cationic organic dyestuff commonly used for tracer studies in water research, on activated carbon.

For each trial, a given amount of activated carbon indicated below in milligrams was measured into a small flask. Table 1 shows the values of the parameters of the two isotherms and the related correlation coefficients. Removal of methylene blue by adsorption onto activated carbon. Adsorption of textile wastes containing methylene blue. Pdf adsorption of methylene blue on activated carbon fiber.

In this paper, the enhanced adsorption of methylene blue mb dye ion on the activated carbon ac modified by three surfactants in. The effect of different percentage additional efb into absorption process. Methylene blue mb with heteropolyaromatic structure, which presents a strong inhibitive function for biologic degradation and is very difficult to be degraded into small inorganic molecules by using common methods, is usually employed as the model dye to study adsorption properties of activated carbon ac materials ahmed and dhedan, 2012. The kinetics of adsorption of methylene blue from aqueous solution onto activated carbon prepared from palm kernel shell has been investigated. The major concerning problem of these dyes and pigments industries is colored effluent. Kinetics of adsorption of methylene blue onto activated. The influence of various factors such as adsorbent concentration, initial dye concentration, temperature, contact time, ph, and surfactant was studied. An activated carbon was prepared from pea shells and used for the removal of methylene blue mb from aqueous solutions. Methylene blue adsorption on activated carbon prepared from posidonia oceanica l. Adsorption of methylene blue on lowcost adsorbents. The time dependent studies showed a rapid adsorption in the first ten minute. Pdf adsorption study of methylene blue and eriochrome. In this paper, the enhanced adsorption of methylene blue mb dye ion on the activated carbon ac modified by three surfactants in aqueous solution was researched. Adsorption of methylene blue onto activated carbon developed.

Although commercial activated carbon is a preferred adsorbent for color removal, its widespread use is restricted due to its relatively high cost. Pdf adsorption of methylene blue on activated carbon. Chapter7 adsorption of methylene blue onto microwave oven. Pseudo second order kinetic plot for adsorption of methylene blue on activated carbon. Removal of methylene blue from aqueous solution by. Adsorption of methylene blue from industrial effluent using. Freundlich adsorption isotherm of methylene blueactivated carbon adsorption at 30 c. The adsorption of methylene blue mb on activated carbon. Industrial waste lignin, h 3 po 4, activated carbon, adsorption, isotherms. To test the langmuir and freundlich adsorption models, you will need to calculate x and c for each trial. The effect of contact time, solution ph and adsorbent dosage. Methylene blue adsorption from aqueous solution by activated. The adsorption of methylene blue mb onto activated carbon produced from flamboyant pods delonix regia and obtained under optimized conditions ac op was carried out in this work.

The removal of methylene blue mb from aqueous solution using activated carbon ac has been investigated. Therefore, the aim of this research was to prepare activated carbon from tea seed shells by using a zncl 2 activation method, to investigate its textural and chemical surface characterization, and to study its adsorption of methylene blue mb including kinetics, equilibrium, and thermodynamics studies. Adsorption of methylene blue onto activated carbon impregnated with koh using cocoa shell 12. Activated carbon is a carbon based amorphous material having high surface area and high porosity. Batch adsorption of methylene blue methylene blue dye solution at different initial concentration 15, 20 and 25 ppm was prepared. The equilibrium data for methylene blue adsorption well fitted to the langmuir equation, with maximum monolayer adsorption capacity of 500. Pdf adsorption of methylene blue onto activated carbon. Merck, india and was used without further purification. The adsorption isotherm was found to follow the langmuir model. This work investigates the adsorption of methylene blue mb onto activated carbons produced from date pits using equilibrium isotherms. Adsorption of methylene blue onto activated carbon produced from tea camellia sinensis l.

Bamboo, an abundant and inexpensive natural resource in malaysia was used to prepare activated carbon by physiochemical activation with potassium hydroxide koh and carbon dioxide co 2 as the activating agents at 850 c for 2 h. Production of rubber seed pericarp based activated carbon. Adsorption of methylene blue from aqueous solution has been investigated on activated charcoal, silica gel and silica clay by spectrophotometric method. Langmuir, freundlich and bet isotherms were used to study and compare the effect of contact time, effect of ph. Sep 10, 2012 therefore, the aim of this research was to prepare activated carbon from tea seed shells by using a zncl 2 activation method, to investigate its textural and chemical surface characterization, and to study its adsorption of methylene blue mb including kinetics, equilibrium, and thermodynamics studies. The experimental equilibrium data were analyzed using the isotherms of langmuir, freundlich, jovanovic, harkinsjura, tempkin, redlichpeterson, toth, radkeprausnitz, sips, viethsladek, and brouers.

The fitting of the kinetic study showed that the second order model was the best because r 2 was of 0. Comparative adsorption isotherms and modeling of methylene. Preparation and characterization of activated carbons from. For methylene blue analysis, by using uvvisible spectrophotometer, the wavelength use is 665nm. The effect of system variable such as concentration, ph, contact time and adsorbent dosage are investigated. A batch sorption model based on the assumption of the pseudo first and second order mechanism, were applied to predict the rate constants. Adsorption of methylene blue on activated carbon produced. The effect of experimental parameters such as ph, dye concentration and temperature were studied on the adsorption process. Methylene blue and brilliant green dyes removal from aqueous. The monolayer sorption capacity of activated carbon prepared from pea shell for mb was found. Pdf adsorption of methylene blue from aqueous solution has been investigated on activated charcoal, silica gel and silica clay by. A comparison is also made between two isotherms plotted in fig.